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dc.contributor.authorBüyüksağiş, Aysel
dc.contributor.authorÇiçek, H.Y.
dc.contributor.authorBütün, V.
dc.date.accessioned2019-12-20T07:20:02Z
dc.date.available2019-12-20T07:20:02Z
dc.date.issued2019en_US
dc.identifier.citationBuyuksağiş, A. & Çiçek, H.Y. & Bütün, V. “Tertiary Amine Methacrylate Based Polymers As Corrosion Inhibitors İn Hcl Solution. Part Iı”, Protection Of Metals And Physical Chemistry Of Surfaces, 2019, 5, Pp. 963–972. © Pleiades Publishing, Ltd., 2019. Issn 2070-2051, Doı: 10.1134/S207020511905006xen_US
dc.identifier.urihttps://www.doi.org/10.1134/S207020511905006X
dc.identifier.urihttps://hdl.handle.net/11630/7568
dc.description.abstractIn this study, the inhibitive performance of novel synthesised water-soluble of different molecular weight diblock copolymers of derivative methyl methacrylate (VB84, VB206, VB207, VB361, VB371,VB406) on the corrosion behaviour of AISI 304 stainless steel in 10–3 M HCl containing various concentrations of polymers was investigated using potentiodynamic polarisation, electrochemical impedance spectroscopy (EIS), scanning electron microscopy(SEM), energy dispersive X-ray analysis (EDX), atomic force microscopy (AFM) and inductively coupled plasma optical emmision spectrometry (ICP-OES) methods. Polarisation curves indicated that all studied polymers were acting as mixed type inhibitors. All electrochemical measurements showed that inhibition efficiencies increased with increasing polymer concentration. It was determined that the increase of inhibitor efficiency by concentration resulted from the adsorption of polymers to metal surface, and the adsorption fitted to the Langmuir adsorption equation. The variation in inhibitive efficiency mainly depends on the type and the nature of the substituents present in the polymer molecule and also depends on the molecular weight of the polymer. The best inhibition in 10-3 M HCl shows VB84 homopolymer. Surface images obtained with SEM, EDX, and AFM methods determined by verifying these results that inhibitors decrease the dissolution of metal, prevented the corrosion.en_US
dc.language.isoengen_US
dc.publisherPleiades Publishing, Ltden_US
dc.identifier.doi10.1134/S207020511905006Xen_US
dc.rightsinfo:eu-repo/semantics/restrictedAccessen_US
dc.subjectCorrosionen_US
dc.subjectPolymeren_US
dc.subjectAdsorptionen_US
dc.subjectInhibitoren_US
dc.subjectAISI 304 Stainless Steelen_US
dc.subjectMethyl Methacrylateen_US
dc.subjectDiblock Copolymeren_US
dc.titleTertiary amine methacrylate based polymers as corrosion ınhibitors in hcl solution. Part IIen_US
dc.typearticleen_US
dc.relation.journalProtection of Metals and Physical Chemistry of Surfaces,en_US
dc.departmentFen-Edebiyat Fakültesien_US
dc.authorid0000-0001-8911-7157en_US
dc.identifier.volume5en_US
dc.identifier.startpage963en_US
dc.identifier.endpage972en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.contributor.institutionauthorBüyüksağiş, Aysel


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