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Novel functional copolymers based on glycidyl methacrylate: Synthesis, Characterization, and Polymerization kinetics

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Makale Dosyası (1.116Mb)

Date

01.02. 201

Author

Erol, İbrahim
Devrim, Derya Nimet
Çiftçi, Hakan
Ersoy, Bahri
Ciğerci, İ. Hakkı

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Abstract

A new methacrylate monomer 2-(4-nitrophenyl)-2-oxoethyl-2-methacrylate (NFM) was synthesized and its radical copolymerization with glycidyl methacrylate (GMA) was studied in 1,4-dioxane solution at 65 C using 2,2 0 -azobisisobutyronitrile as an initiator. The synthesized monomer and copolymers were characterized by FTIR, 1 H and 13 C-NMR spectroscopy. The analysis of reactivity ratios revealed that NFM is less reactive than GMA, and copolymers formed are statistically in nature. Thermogravimetric analysis of the polymers reveals that the thermal stability of the copolymers increases with an increasing in the mole fraction of NFM in the copolymers. Glass transition temperatures of the copolymers decreased with an increasing of NFM molar fraction in copolymers. In addition, according to the results obtained from the contact angle and zeta potential measurements the hydrophobic character of the polymer decreases (it means surface free energy increases) and its zeta potential becomes more negative with increase of NFM ratio in the copolymer. Polymers with carbonyl functional groups have been particularly interesting because of their use as photoresists.

Source

Journal Of Macromolecular Science, Part a: Pure And Applied Chemıstry

Volume

54

Issue

7

URI

https://www.doi.org/10.1080/10601325.2017.1320747
https://hdl.handle.net/11630/7681

Collections

  • Makaleler [36]
  • Scopus İndeksli Yayınlar Koleksiyonu [133]
  • WoS İndeksli Yayınlar Koleksiyonu [88]



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